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PEGFOSIMERE MANGANESE
PEGFOSÍMERO MANGANESO
POLYMER NANOPARTICLES SYNTHESIZED FROM TETRAMETHYL P,P'-[1,7- BIS(TRIETHOXYSILYL)HEPTANE-4,4-DIYL]BISPHOSPHONATE (~52 MOLECULES PER PARTICLE ON AVERAGE) BY (I) HYDROLYSIS OF THE TRIETHOXYSILYL GROUPS AND ~75% OF THE DIMETHYL PHOSPHONATE GROUPS AND CONDENSATION OF THE RESULTING BISSILANETRIOL TO A POLYMERIC NETWORK WITH SI-O-SI LINKAGES, (II) COATING OF THE CORE PARTICLES BY HYDROLYSIS OF ALPHA-({3,5-BIS[3- (TRIETHOXYSILYL)PROPOXY]PHENYL}METHYL)-OMEGA-METHOXYPOLY(OXYETHYLENE) (~18 MOLECULES PER PARTICLE ON AVERAGE) AND CONDENSATION OF THE RESULTING SILANETRIOL GROUPS WITH SURFICIAL SILANOL GROUPS, AND (III) ADDITION OF A MANGANESE(2+) SALT TO FORM HYDRATED POLYMERIC AMMONIUM MANGANESE(2+) SODIUM (APPROXIMATELY EQUAL TO 29:13:65) PHOSPHONATE COMPLEXES